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CO2 Batteries That Store Grid Energy Take Off Globally

https://spectrum.ieee.org/co2-battery-energy-storage
43•rbanffy•4h ago

Comments

AndrewDucker•1h ago
No mention of round-trip efficiencies, and claims are that it's 30% cheaper than Li-Ion. Which might give it an advantage for a while, but as Li-Ion has become 80% cheaper in the last decade that's not something which will necessarily continue.

Great if it can continue to be cheaper, of course. Fingers crossed that they can make it work at scale.

cogman10•1h ago
I'm seeing round trip efficiencies around 75%.

That's not terrible.

These things would probably pair well with district heating and cooling.

3eb7988a1663•33m ago
That is shockingly good. EIA reports existing grid scale battery round trip is like 82% which do not have moving parts.

  ...in 2019, the U.S. utility-scale battery fleet operated with an average monthly round-trip efficiency of 82%, and pumped-storage facilities operated with an average monthly round-trip efficiency of 79%.... 
https://www.eia.gov/todayinenergy/detail.php?id=46756
lambdaone•7m ago
A theoretical study shows 77%, which is in the same ballpark: https://www.sciencedirect.com/science/article/pii/S136403212...

A few percent here of there is not that important if the input energy is cheap enough.

Gys•1h ago
Lithium supply is limited. So an alternative based on abundant materials is interesting for that reason I guess?
_aavaa_•1h ago
Lithium is not that limited, current reserves are based on current exploration. More sources will be found and exploited as demand grows.

And if you want an alternative, sodium batteries are already coming online.

standeven•1h ago
It's also very recyclable, so big batteries that reach end of life can contribute back to the lithium supply.
cogman10•28m ago
In fact, the limiting element for Li chemistries is generally the Nickel. Pretty much everything else that goes into these chemistries is highly available. Even something like Cobalt which is touted as unavailable is only that way because the industrial uses of cobalt is basically only li batteries. It's mined by hand not because that's the best way to get it, but because that's the cheapest way to get the small amount that's needed for batteries.

Sodium iron phosphate batteries, if Li prices don't continue to fall, will be some of the cheapest batteries out there. If they can be made solid state then you are looking at batteries that will dominate things like grid and home power storage.

Tade0•1h ago
There are over 200 billion tonnes of lithium in seawater, it's just the least economical out of all sources of this element.

There are plenty more, but they're explored only when there's a price hike.

cogman10•22m ago
AFAIK, the brine pits are pretty economical, they just require ocean access.

What I'm somewhat surprised about is that we've not seen synergies with desalination and ocean mineral extraction. IDK why the brine from a desalination plant isn't seen as a prime first step in extraction lithium, magnesium, and other precious minerals from ocean water.

scotty79•1h ago
Also sodium batteries are coming to the market at a fraction of the cost.

"We’re matching the performance of [lithium iron phosphate batteries] at roughly 30% lower total cost of ownership for the system." Mukesh Chatter, cofounder and CEO, Alsym Energy

lambdaone•3m ago
I see this as complementary to other energy storage systems, including sodium ion batteries; each will have its own strengths and weaknesses. I expect energy storage density cost will be the critical parameter here, as this looks best suited to do diurnal storage for solar power systems near out-of-town predictable power consumers like data centers.
Herring•55m ago
Efficiency isn't that important if the input cost is low enough. Basically the utility is throwing it away (curtailment) so you probably can too. CAPEX is really the most important part of this.

CO2 batteries scale by adding more steel tanks or larger bladders. The expensive components (compressors/turbines) stay the same. Therefore unlike Li-ion, the CO2 battery becomes exponentially more cost-effective as the total required capacity/duration increases.

readthenotes1•1h ago
Does pure-ish CO2 have advantages over regular air or the freon-like substance used in air conditioning?

How much energy us used to purify and maintain the CO2?

cogman10•1h ago
It's pretty cheap to acquire a boatload of and, assuming you don't get it directly from burning fossil fuels, there's really no environmental harms of it leaking into the atmosphere. [1]

[1] https://en.wikipedia.org/wiki/Carbon_capture_and_storage

zahlman•1h ago
> CCS could have a critical but limited role in reducing greenhouse gas emissions.[6] However, other emission-reduction options such as solar and wind energy, electrification, and public transit are less expensive than CCS and are much more effective at reducing air pollution. Given its cost and limitations, CCS is envisioned to be most useful in specific niches. These niches include heavy industry and plant retrofits.[8]: 21–24

> The cost of CCS varies greatly by CO2 source. If the facility produces a gas mixture with a high concentration of CO2, as is the case for natural gas processing, it can be captured and compressed for USD 15–25/tonne.[66] Power plants, cement plants, and iron and steel plants produce more dilute gas streams, for which the cost of capture and compression is USD 40–120/tonne CO2.[66]

... And then for this usage, presumably you'd have to separate the CO2 from the rest of the gas.

analog31•1h ago
It's easy to liquefy, so it has a density advantage over air, and would be bad if released but not super bad.
3eb7988a1663•30m ago
Suffocation seems like the most relevant concern in the event of a catastrophic leak.
ajb•1h ago
These days CO2 is actually quite commonly used in air-conditioners as a refrigerant, R-744. Fluorinated gases like Freon are being phased out due to being even worse for global warming.
lambdaone•1h ago
This seems almost too good to be true, and the equipment is so simple that it would seem that this is a panacea. Where are the gotchas with this technology?

Clearly power capacity cost (scaling compressors/expanders and related kit) and energy storage cost (scaling gasbags and storage vessels) are decoupled from one another in this design; are there any numbers publicly available for either?

zahlman•1h ago
Well, it isn't going to sink enough CO2 to move the needle:

> If the worst happens and the dome is punctured, 2,000 tonnes of CO2 will enter the atmosphere. That’s equivalent to the emissions of about 15 round-trip flights between New York and London on a Boeing 777. “It’s negligible compared to the emissions of a coal plant,” Spadacini says. People will also need to stay back 70 meters or more until the air clears, he says.

So it's really just about enabling solar etc.

api•2m ago
It’s a battery not a sequestration technology.
to11mtm•10m ago
I don't know numbers but I at least remember my paintball physics;

As far as the storage vessel, CO2 has much lower pressure demands than something like, say, hydrogen. On something like a paintball marker the burst disc (i.e. emergency blow off valve) for a CO2 tank is in the range of of 1500-1800PSI [0].

A compressed air tank that has a 62cubic inch, 3000PSI capacity, will have a circumference of 29cm and a length close to 32.7cm, compared to a 20oz CO2 tank that has a circumfrence of 25.5cm and a length of around 26.5cm [1]. The 20oz tank also weighs about as much 'filled' as the Compressed air tank does empty (although compressed air doesn't weigh much, just being through here).

And FWIW, that 62/3000 compressed air vs 20oz CO2 comparison... the 20oz of CO2 will almost certainly give you more 'work' for a full tank. When I was in the sport you needed more like a 68/4500 tank to get the same amount of use between fills.

Due to CO2's lower pressures and overall behavior, it's way cheaper and easier to handle parts of this; I'm willing to bet the blowoff valve setup could in fact even direct back to the 'bag' in this case, since the bag can be designed pessimistically for the pressure of CO2 under the thermal conditions. [2]

I think the biggest 'losses' will be in the energy around re-liquifying the CO2, but if the system is closed loop that's not gonna be that bad IMO. CO2's honestly a relatively easy and as long as working in open area or with a fume hood relatively safe gas to work with, so long as you understand thermal rules around liquid state [also 2] and use proper safety equipment (i.e. BOVs/burst discs/etc.)

[0] - I know there are 3k PSI burst discs out there but I've never seen one that high on a paintball CO2 tank...

[1] - I used the chart on this page as a reference: https://www.hkarmy.com/products/20oz-aluminum-co2-paintball-...

[2] - Liquid CO2 does not like rapid thermal changes or sustained extreme heat; This is when burst discs tend to go off. But it also does not work nearly as well in cold weather, especially below freezing. Where this becomes an issue is when for one reason or another liquid CO2 gets into the system. This can be handled in an industrial scenario with proper design I think tho.

lambdaone•9m ago
Fantastic detail, thank you.
scotty79•1h ago
"First, a compressor pressurizes the gas from 1 bar (100,000 pascals) to about 55 bar (5,500,000 pa). Next, a thermal-energy-storage system cools the CO2 to an ambient temperature. Then a condenser reduces it into a liquid that is stored in a few dozen pressure vessels, each about the size of a school bus. The whole process takes about 10 hours, and at the end of it, the battery is considered charged.

To discharge the battery, the process reverses. The liquid CO2 is evaporated and heated. It then enters a gas-expander turbine, which is like a medium-pressure steam turbine. This drives a synchronous generator, which converts mechanical energy into electrical energy for the grid. After that, the gas is exhausted at ambient pressure back into the dome, filling it up to await the next charging phase."

alexchamberlain•1h ago
Would this be effective at smaller volumes? Could it get down to say the size of a washing machine for use at home?
lambdaone•6m ago
Very unlikely. All the technologies involved work best at scale; for example, the area-to-volume ratio of the liquid gas storage vessel is a critical parameter to keep energy losses low.
standardUser•57m ago
I've been waiting for large-scale molten salt/rock batteries to take off. They've existed at utility scale for years but are still niche. They're not especially responsive and I imagine a facility to handle a mass amount of molten salt is not the easiest/cheapest thing to build.

This sounds better in every way.

creativeSlumber•51m ago
what happens if that large enclosure fails and the CO2 freely flows outside?

That enclosure has a huge volume - area the size of several football fields, and at least 15 stories high. The article says it holds 2k tons of co2, which is ~1,000,000 cubic meters in volume.

CO2 is denser than air will pool closer to the ground, and will suffocate anyone in the area.

See https://en.wikipedia.org/wiki/Lake_Nyos_disaster

Edit: It holds 2k tons, not 20K tons.

tonfa•46m ago
> People will also need to stay back 70 meters or more until the air clears, he says.
Hnrobert42•44m ago
The last section of TFA is called "What happens if the dome is punctured?". The answer: a release of CO2 equal to about 15 transatlantic flights. People have to stand back 70m until it clears.

It would not be good, but it wouldn't be Bhopal. And there are still plenty of factories making pesticides.

creativeSlumber•25m ago
Comparing it to X flights maybe correct from a greenhouse emissions standpoint, but extremely misleading from a safety perspective. A jet emits that co2 spread over tens of thousands of miles. The problem here is it all pooled in one location.

Also that statement of 70 meters seem very off, looking at the size of the building. What leads to suffocation is the inability to remove co2 from your body rather than lack of oxygen, and thus can be life threatening even at 4% concentration. It should impact a much much larger area.

epgui•14m ago
It's a gas in an open space, it diffuses very quickly.
ben_w•2m ago
https://en.wikipedia.org/wiki/Limnic_eruption

I don't know the safety limits for this quantity, I hope the "70 meters" claim was by someone who modelled it carefully rather than a gut check.

to11mtm•1m ago
Yep. When I had to fill CO2 tanks at a paintball shop yes there were times that I had to open a door (I mean we were talking a lot of fills in short time, btw fills had to start with draining the tank's existing volume so I could zero out the scale) but even indoors a door+fan was enough to keep even the nastiest of sale days OSHA compliant.

Also a 'puncture' is very different from the gasbag mysteriously vanishing from existence; My only other thought is that in cold regions (I saw wisconsin mentioned in the article) CO2 does not diffuse quite as fast and sometimes visibly so...

buckle8017•7m ago
So it's a compressed air facility but it's using dry CO2 because it makes the process easier and CO2 is cheap.

Not a carbon sequestration thing, but will likely fool some people into thinking it is.

So the question is, how much does it cost? The article is completely silent on this, as expected.

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